Hi - Just picked up a book on Thomas James, MA, Llandysul today and having just put in his name into google came up with your query under Ancestry. I only picked up the book as I am researching my family history who originated from Llandysul and the surrounding area. With regard to your query I am pleased to inform you that in the book on "Cyfrol Goffa" on p.38 it does say that T.James married on 8 August 1888 long after his middle age a Miss Mary Morris Penmorfa sister to the late Rev. J. G. Morris, Indepdendent Minister from Newport Pembs. He died on 6 September 1915 aged 80 in Llandysul and is buried in Seion Chapel, Llandysul.
I hope that the above information will be of use to you.