Are you still seeking information? Your query on RootsWeb/Ancestry is rather dated now.
If you are, the published records of St. Francis de Sales Church in Waterville (vol. 1; Robert Chenard) state on p. 173 that Napoleon "Paul" Morin was son of Jean Morin & Lucie Paquet and that he married 9 August 1897 Ida-Etta Boucher (daughter of Zephrin and Marie Boucher).
Bob Chenard (compiler) is probably the best French-Canadian genealogist in the area. His web site (google: <"french connection" chenard> contains a lot of information and you really ought to browse through it. Bob has several books of transcribed F-C records and they should be listed on the site. If your ancestors came from Beauce County (as most French-Canadians in this area did), he has records to trace you way back. Using Bob as a source, Cindy Spaulding has done this on her site "WatervilleGenalogy".
I am in Fairfield (adjacent to Waterville) and have access to records here but I am guessing that it is the earlier records that you want.