According to her marriage bond her mother was Mary Freeman, bondsmen were Henry R. Bonnett and Jacob Straley dated Jul 12, 1838. Her name is listed as Katherine Ann Freeman.
Marriage date Jul 14, 1838 by Henry R. Bonnett
Jacob & Catherine are listed in the Lewis Co., VA. 1850 census # 1343-1368 with six children and a Susan Straley 32 VA in their home.
Next door census# 1344-1369 is a Mary Freeman 48 VA, Francis Suttle 50 VA farmer and Layfayett Freeman 23 VA farmer that may well be Catherines mother and a brother.
Checking the 1840 Lewis Co., VA census I do not find any Freemans listed nor in 1830.