Could this be your family in 1901? If so, It appears they may have had a more adventurous journey than expected, for it looks more like your Biffin family came from Ireland, than England.
5 41 46 Biffin Charles M Head M Dec 25 1852 48, b. QUE r, Irish, Labourer
5 42 46 Biffin Jane F Wife M Aug 13 1854 46, b. Scotland, Scotch
5 43 46 Biffin Harry M Son S Mar 6 1883 18, b. ON u, Lithograher
5 44 46 Biffin Annie F Daughter S Dec 1 1885 15, b. ON u, Student
5 45 46 Biffin Marid F Daughter S Nov 13 1887 13, b. ON u, Student
5 46 46 Biffin Fern F Daughter S Aug 22 1892 8, b. ON u, Student
5 47 46 Biffin Edna F Daughter S Sep 9 1894 6, b. ON u, Student
5 48 46 Biffin Elsie F Daughter S Dec 23 1897 3, b. ON u
1901 Census of Canada
Subdistrict: Ward/Quartier No. 2, TORONTO (East/Est) (City/Cité), ONTARIO
District Number: 117
Subdistrict Number: b-2
Archives Microfilm: T-6498

The Biffin family in 1881:
Charles BIFFIN M Male Irish 29 Q <Quebec> Teamster Presbyterian
Jane BIFFIN M Female Scottish 28 Scotland Presbyterian
Magie BIFFIN Female Irish 7 O <Ontario> Presbyterian
Lizie BIFFIN Female Irish 5 O <Ontario> Presbyterian
Margret HENRY W Female Scottish 80 Scotland Presbyterian
Census Place St Thomas Ward, Toronto, York, Ontario
Family History Library Film 1375882
NA Film Number C-13246
District 134
Sub-district C
Division 1
Page Number 109
Household Number 577

Marriage of Lizzie Biffin;
#001104-98 - Thomas Edward ARNALL, 21, Toronto, 186 River St Toronto, b, wood finisher, s/o Thomas ARNALL & Mary ST.ALBIN, married Elizabeth BIFFIN, 22, Toronto, 56 Trinity St Toronto, s, d/o Charles BIFFIN & Jane CRUICKSHANK, witn: James ADAMS, C.L. ADAMS, both 134 Seaton St Toronto, married 31 December 1897, 134 Seaton St