Most excellent! I indeed found the marriage between Job Male and Elizabeth Scott on the exact date you give. However, I've found at least with this branch of my family they interchanged middle and surnames very often. I've found records on familysearch.org that Elizabeth Scott's full name was actually Adelaide Elizabeth Scott; the record corresponds with dates and names which make me reasonably sure it's the same girl.
I've never seen a record of Job Male's son Job, but if it was from his first wife, I have her as Mary Louisa Scott. All I know is she gave birth to Mary Louise Male on March 28 1866 and died April 22 of the same year. I do have record of Ida Male, and the Madie born in 1878 may have been the Hellen MM Male I found in the 1881 Canadian census in the Male household. Claire was actually Vina Clair, and she married my ancestor Charles Glenney after his first wife's death (her sister, Mary Louise) in 1903. Don't have a date on that marriage.
As Ambrose Male came from England, that goes to say his granddaughter Vina Clair wasn't fully blood Native American, but it's possible that her mother Adelaide Elizabeth was? I don't suppose you have any more pedigree information on Libby, do you?