Brenda, that interesting. There was no mention of his two marriages in my family (he is my great grandfather). Here is some other information you might want to add:
He married Lucy Ellen LIBBY on 16 Nov 1891, St. Francis de Sales Church, Waterville, ME. (Marriage Certificate). His children were:
+Louis Albert POULIN
+Beatrice POULIN
Also, on Levi Pooler, you can probably narrow his death probably between 1880 and 1882. The 1882 Brewer directory shows "Pooler, Angeline, widow of Levi, h. Main, nr. Pendelton ct, S.B." He was alive in 1880 (or at least when they did the 1880 census).