Its definitely SASTRE which pertains to sewing, possibly a tailor. I could make out TENDERA for Juana Reyes, meaning she's involved in some selling activity.
But im at a loss as to what that word is for Telesfora Segismundo's profession. . . sorry, i cant even get that first letter. . .it seems like an A at first glance but its not. As for the marital status, i could only surmise that CDO means CASADO or married while the markings below that word could be a ditto symbol.
Perhaps this resource from Family Search on Spanish Genealogical Word List would help youhttps://familysearch.org/learn/wiki/en/Spanish_Genealogical_...
I hope some others could help you decipher these.