Hello,
It is on the North Smithfield North Providence line and it was a catholic orphanage. It is still part of the church but no longer an orphanage. If you call the catholic diocesse they might be able to tell you if and where any records might be. You can also try DCYF in Providence. If you family went through them they will have records and you can request to see them. It takes a little while for them to find and get them but they try their best to help. I hope this has helped some. Good luck in your search.